Friday, July 9, 2010

1.1.5 Mass + Shape & Size

Mass
Main article: Atomic mass
Because the large majority of an atom's mass comes from the protons and neutrons, the total number of these particles in an atom is called the mass number. The mass of an atom at rest is often expressed using the unified atomic mass unit (u), which is also called a Dalton (Da). This unit is defined as a twelfth of the mass of a free neutral atom of carbon-12, which is approximately 1.66 × 10−27 kg. Hydrogen-1, the lightest isotope of hydrogen and the atom with the lowest mass, has an atomic weight of 1.007825 u. An atom has a mass approximately equal to the mass number times the atomic mass unit. The heaviest stable atom is lead-208,[68] with a mass of 207.9766521 u.
As even the most massive atoms are far too light to work with directly, chemists instead use the unit of moles. The mole is defined such that one mole of any element always has the same number of atoms (about 6.022 × 1023). This number was chosen so that if an element has an atomic mass of 1 u, a mole of atoms of that element has a mass close to 0.001 kg, or 1 gram. Because of the definition of the unified atomic mass unit, carbon has an atomic mass of exactly 12 u, and so a mole of carbon atoms weighs exactly 0.012 kg.

Shape and size
Main article: Atomic radius
Atoms lack a well-defined outer boundary, so their dimensions are usually described in terms of an atomic radius. This is a measure of the distance out to which the electron cloud extends from the nucleus. However, this assumes the atom to exhibit a spherical shape, which is only obeyed for atoms in vacuum or free space. Atomic radii may be derived from the distances between two nuclei when the two atoms are joined in a chemical bond. The radius varies with the location of an atom on the atomic chart, the type of chemical bond, the number of neighboring atoms (coordination number) and a quantum mechanical property known as spin. On the periodic table of the elements, atom size tends to increase when moving down columns, but decrease when moving across rows (left to right). Consequently, the smallest atom is helium with a radius of 32 pm, while one of the largest is caesium at 225 pm.
When subjected to external fields, like an electrical field, the shape of an atom may deviate from that a sphere. The deformation depends on the field magnitude and the orbital type of outer shell electrons, as shown by group-theoretical considerations. Aspherical deviations might be elicited for instance in crystals, where large crystal-electrical fields may occur at low-symmetry lattice sites.Significant ellipsoidal deformations have recently been shown to occur for sulfur ions in pyrite-type compounds.
Atomic dimensions are thousands of times smaller than the wavelengths of light (400–700 nm) so they can not be viewed using an optical microscope. However, individual atoms can be observed using a scanning tunneling microscope. To visualize the minuteness of the atom, consider that a typical human hair is about 1 million carbon atoms in width. A single drop of water contains about 2 sextillion (2 × 1021) atoms of oxygen, and twice the number of hydrogen atoms. A single carat diamond with a mass of 2 × 10-4 kg contains about 10 sextillion (1022) atoms of carbon.[note 2] If an apple were magnified to the size of the Earth, then the atoms in the apple would be approximately the size of the original apple.

No comments:

Post a Comment